Colloque

Possible coordination between halides of group IV elements and the triple bond of diethylaminoacetonitrile as ligand

S. C. Jain

R. Rivest

Membre a labase

S. C. Jain

Résumé du colloque

Coordination compounds between diethylaminoacetonitrile and halides of group IV elements have been prepared. The analytical results, the molecular weight determination and the infrared spectroscopic studies are consistent with the presence of dies give good evidence of chelate formation through the triple bond of the ligand and the nitrogen of the amino group. The obtention of such chelates has been found to be limited to the aminonitriles R2N-(CH2)n-CN in which n was equal to 1 and 2.