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In recent years, the focus of solid state polymer physical chemistry has increasingly shifted towards the definition and the phenomenology of various intermediate crystalline structures, i.e., those transformation of the initial spatial geometries at the backbone level that are capable of generating complex macromolecular morphologies which manifest themselves in the final properties of the solid materials. Optically pure polymers are ideal models, both from experimental and theoretical perspectives, for the study of the chirality-induced morphologies in the advanced supermacromolecular organizations which are predominantly found in biopolymers. Structural analyses of crystallizing polymers capitalized on molecular modeling capability to perform energy calculations …